Selenium Element Information, Facts, Properties, Trends, Uses, Comparison with other elements
Selenium is a chemical element with symbol Se and atomic number 34. It is a nonmetal with properties that are intermediate between those of its periodic table column-adjacent chalcogen elements sulfur and tellurium. It rarely occurs in its elemental state in nature, or as pure ore compounds.
It belongs to group 16 of the periodic table having trivial name chalcogens. You can also download Printable Periodic Table of Elements Flashcards for Selenium in a PDF format.
Selenium Facts
Read key information and facts about element Selenium
Name | Selenium |
Atomic Number | 34 |
Atomic Symbol | Se |
Atomic Weight | 78.96 |
Phase | Solid |
Color | Gray |
Appearance | black, red, and gray (not pictured) allotropes |
Classification | Other Nonmetal |
Natural Occurance | Primordial |
Group in Periodic Table | 16 |
Group Name | oxygen family |
Period in Periodic Table | period 4 |
Block in Periodic Table | p-block |
Electronic Configuration | [Ar] 3d10 4s2 4p4 |
Electronic Shell Structure (Electrons per shell) | 2, 8, 18, 6 |
Melting Point | 494 K |
Boiling Point | 958 K |
CAS Number | CAS7782-49-2 |
How to Locate Selenium on Periodic Table
Periodic table is arranged by atomic number, number of protons in the nucleus which is same as number of electrons. The atomic number increases from left to right. Periodic table starts at top left ( Atomic number 1) and ends at bottom right (atomic number 118). Therefore you can directly look for atomic number 34 to find Selenium on periodic table.
Another way to read periodic table and locate an element is by using group number (column) and period number (row). To locate Selenium on periodic table look for cross section of group 16 and period 4 in the modern periodic table.
Selenium History
The element Selenium was discovered by J. Berzelius and G. Gahn in year 1817 in Sweden. Selenium was first isolated by J. Berzelius and G. Gahn in 1817. Selenium derived its name from the Greek selene, meaning 'moon'.
Discovered By | J. Berzelius and G. Gahn |
Discovery Date | 1817 in Sweden |
First Isolation | 1817 |
Isolated by | J. Berzelius and G. Gahn |
While working with lead they discovered a substance that they thought was tellurium, but realized after more investigation that it is different.
Selenium Uses
Major uses for selenium are in the glass industry. Its characteristics allow it to decolorize class and make red glass as well. It is used in solar and photocells. In film photography, it is also used as a photographic toner
Selenium Presence: Abundance in Nature and Around Us
The table below shows the abundance of Selenium in Universe, Sun, Meteorites, Earth's Crust, Oceans and Human Body.
ppb by weight (1ppb =10^-7 %) | ppb by atoms (1ppb =10^-7 %) | |
---|---|---|
Abundance in Universe | 30 | 0.5 |
Abundance in Sun | - | - |
Abundance in Meteorites | 13000 | 2900 |
Abundance in Earth's Crust | 50 | 10 |
Abundance in Oceans | 0.45 | 0.035 |
Abundance in Humans | 50 | 4 |
Crystal Structure of Selenium
The solid state structure of Selenium is Simple Monoclinic.
The Crystal structure can be described in terms of its unit Cell. The unit Cells repeats itself in three dimensional space to form the structure.
Unit Cell Parameters
The unit cell is represented in terms of its lattice parameters, which are the lengths of the cell edges Lattice Constants (a, b and c)
a | b | c |
---|---|---|
905.4 pm | 908.3 pm | 1160.1 pm |
and the angles between them Lattice Angles (alpha, beta and gamma).
alpha | beta | gamma |
---|---|---|
π/2 | 1.58493 | π/2 |
The positions of the atoms inside the unit cell are described by the set of atomic positions ( xi, yi, zi) measured from a reference lattice point.
The symmetry properties of the crystal are described by the concept of space groups. All possible symmetric arrangements of particles in three-dimensional space are described by the 230 space groups (219 distinct types, or 230 if chiral copies are considered distinct.
Space Group Name | P121/c1 |
Space Group Number | 14 |
Crystal Structure | Simple Monoclinic |
Number of atoms per unit cell |
The number of atoms per unit cell in a simple cubic, face-centered cubic and body-centred cubic are 1,4,2 respectively.
Selenium Atomic and Orbital Properties
Selenium atoms have 34 electrons and the electronic shell structure is [2, 8, 18, 6] with Atomic Term Symbol (Quantum Numbers) 3P2.
Atomic Number | 34 |
Number of Electrons (with no charge) | 34 |
Number of Protons | 34 |
Mass Number | 79 |
Number of Neutrons | 45 |
Shell structure (Electrons per energy level) | 2, 8, 18, 6 |
Electron Configuration | [Ar] 3d10 4s2 4p4 |
Valence Electrons | 4s2 4p4 |
Valence (Valency) | 6 |
Main Oxidation States | -2, 2, 4, 6 |
Oxidation States | -2, -1, 0, 1, 2, 3, 4, 5, 6 |
Atomic Term Symbol (Quantum Numbers) | 3P2 |
Bohr Atomic Model of Selenium - Electrons per energy level
n | s | p | d | f |
---|
Ground State Electronic Configuration of Selenium - neutral Selenium atom
Abbreviated electronic configuration of Selenium
The ground state abbreviated electronic configuration of Neutral Selenium atom is [Ar] 3d10 4s2 4p4. The portion of Selenium configuration that is equivalent to the noble gas of the preceding period, is abbreviated as [Ar]. For atoms with many electrons, this notation can become lengthy and so an abbreviated notation is used. This is important as it is the Valence electrons 4s2 4p4, electrons in the outermost shell that determine the chemical properties of the element.
Unabbreviated electronic configuration of neutral Selenium
Complete ground state electronic configuration for the Selenium atom, Unabbreviated electronic configuration
1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p4
Electrons are filled in atomic orbitals as per the order determined by the Aufbau principle, Pauli Exclusion Principle and Hund’s Rule.
As per the Aufbau principle the electrons will occupy the orbitals having lower energies before occupying higher energy orbitals. According to this principle, electrons are filled in the following order: 1s, 2s, 2p, 3s, 3p, 4s, 3d, 4p, 5s, 4d, 5p, 6s, 4f, 5d, 6p, 7s, 5f, 6d, 7p…
The Pauli exclusion principle states that a maximum of two electrons, each having opposite spins, can fit in an orbital.
Hund's rule states that every orbital in a given subshell is singly occupied by electrons before a second electron is filled in an orbital.
Atomic Structure of Selenium
Selenium atomic radius is 103 pm, while it's covalent radius is 116 pm.
Atomic Radius Calculated | 103 pm(1.03 Å) |
Atomic Radius Empirical | 115 pm (1.15 Å) |
Atomic Volume | 16.385 cm3/mol |
Covalent Radius | 116 pm (1.16 Å) |
Van der Waals Radius | 190 pm |
Neutron Cross Section | 11.7 |
Neutron Mass Absorption | 0.0056 |
Spectral Lines of Selenium - Atomic Spectrum of Selenium
A spectral line is a dark or bright line in an otherwise uniform and continuous spectrum, resulting from an excess or deficiency of photons in a narrow frequency range, compared with the nearby frequencies. Spectral lines are often used to identify atoms and molecules.
Spectral lines are the result of interaction between a quantum system and a single photon. A spectral line may be observed either as an emission line or an absorption line.
Spectral lines are highly atom-specific, and can be used to identify the chemical composition of any medium. Several elements, including helium, thallium, and caesium, were discovered by spectroscopic means. They are widely used to determine the physical conditions of stars and other celestial bodies that cannot be analyzed by other means.
Emission spectrum of Selenium
Absorption spectrum of Selenium
Selenium Chemical Properties: Selenium Ionization Energies and electron affinity
The electron affinity of Selenium is 195 kJ/mol.
Valence | 6 |
Electronegativity | 2.55 |
ElectronAffinity | 195 kJ/mol |
Ionization Energy of Selenium
Ionization energy is the amount of energy required to remove an electron from an atom or molecule.in chemistry, this energy is expresed in kilocalories per mole (kcal/mol) or kilojoules per mole (kJ/mol).
Refer to table below for Ionization energies of Selenium
Ionization energy number | Enthalpy - kJ/mol |
---|---|
1st | 941 |
2nd | 2045 |
3rd | 2973.7 |
4th | 4144 |
5th | 6590 |
6th | 7880 |
7th | 14990 |
Selenium Physical Properties
Refer to below table for Selenium Physical Properties
Density | 4.819 g/cm3(when liquid at m.p density is $3.99 g/cm3) |
Molar Volume | 16.385 cm3/mol |
Elastic Properties
Young Modulus | 10 |
Shear Modulus | 3.7 GPa |
Bulk Modulus | 8.3 GPa |
Poisson Ratio | 0.33 |
Hardness of Selenium - Tests to Measure of Hardness of Element
Mohs Hardness | 2 MPa |
Vickers Hardness | - |
Brinell Hardness | 736 MPa |
Selenium Electrical Properties
Electrical resistivity measures element's electrical resistance or how strongly it resists electric current.The SI unit of electrical resistivity is the ohm-metre (Ω⋅m). While Electrical conductivity is the reciprocal of electrical resistivity. It represents a element's ability to conduct electric current. The SI unit of electrical conductivity is siemens per metre (S/m).
Selenium is a -. Refer to table below for the Electrical properties of Selenium
Electrical conductors | - |
Electrical Conductivity | - |
Resistivity | - |
Superconducting Point | - |
Selenium Heat and Conduction Properties
Thermal Conductivity | 0.52 W/(m K) |
Thermal Expansion | - |
Selenium Magnetic Properties
Magnetic Type | Diamagnetic |
Curie Point | - |
Mass Magnetic Susceptibility | -4e-9 m3/kg |
Molar Magnetic Susceptibility | -3.16e-10 m3/mol |
Volume Magnetic Susceptibility | -0.0000193 |
Optical Properties of Selenium
Refractive Index | 1.000895 |
Acoustic Properties of Selenium
Speed of Sound | 3350 m/s |
Selenium Thermal Properties - Enthalpies and thermodynamics
Refer to table below for Thermal properties of Selenium
Melting Point | 494 K(220.85 °C, 429.530 °F) |
Boiling Point | 958 K(684.85 °C, 1264.730 °F) |
Critical Temperature | 1766 K |
Superconducting Point | - |
Enthalpies of Selenium
Heat of Fusion | 5.4 kJ/mol |
Heat of Vaporization | 26 kJ/mol |
Heat of Combustion | - |
Selenium Isotopes - Nuclear Properties of Selenium
Selenium has 30 isotopes, with between 65 and 94 nucleons. Selenium has 5 stable naturally occuring isotopes.
Isotopes of Selenium - Naturally occurring stable Isotopes: 74Se, 76Se, 77Se, 78Se, 80Se.
Isotope | Z | N | Isotope Mass | % Abundance | T half | Decay Mode |
---|---|---|---|---|---|---|
65Se | 34 | 31 | 65 | Synthetic | ||
66Se | 34 | 32 | 66 | Synthetic | ||
67Se | 34 | 33 | 67 | Synthetic | ||
68Se | 34 | 34 | 68 | Synthetic | ||
69Se | 34 | 35 | 69 | Synthetic | ||
70Se | 34 | 36 | 70 | Synthetic | ||
71Se | 34 | 37 | 71 | Synthetic | ||
72Se | 34 | 38 | 72 | Synthetic | ||
73Se | 34 | 39 | 73 | Synthetic | ||
74Se | 34 | 40 | 74 | 0.89% | Stable | N/A |
75Se | 34 | 41 | 75 | Synthetic | ||
76Se | 34 | 42 | 76 | 9.37% | Stable | N/A |
77Se | 34 | 43 | 77 | 7.63% | Stable | N/A |
78Se | 34 | 44 | 78 | 23.77% | Stable | N/A |
79Se | 34 | 45 | 79 | Synthetic | Stable | |
80Se | 34 | 46 | 80 | 49.61% | Stable | N/A |
81Se | 34 | 47 | 81 | Synthetic | ||
82Se | 34 | 48 | 82 | 8.73% | Stable | N/A |
83Se | 34 | 49 | 83 | Synthetic | ||
84Se | 34 | 50 | 84 | Synthetic | ||
85Se | 34 | 51 | 85 | Synthetic | ||
86Se | 34 | 52 | 86 | Synthetic | ||
87Se | 34 | 53 | 87 | Synthetic | ||
88Se | 34 | 54 | 88 | Synthetic | ||
89Se | 34 | 55 | 89 | Synthetic | ||
90Se | 34 | 56 | 90 | Synthetic | ||
91Se | 34 | 57 | 91 | Synthetic | ||
92Se | 34 | 58 | 92 | Synthetic | ||
93Se | 34 | 59 | 93 | Synthetic | ||
94Se | 34 | 60 | 94 | Synthetic |
Regulatory and Health - Health and Safety Parameters and Guidelines
The United States Department of Transportation (DOT) identifies hazard class of all dangerous elements/goods/commodities either by its class (or division) number or name. The DOT has divided these materials into nine different categories, known as Hazard Classes.
DOT Numbers | 2658 |
DOT Hazard Class | 6.1 |
NFPA 704 is a Standard System for the Identification of the Hazards of Materials for Emergency Response. NFPA is a standard maintained by the US based National Fire Protection Association.
The health (blue), flammability (red), and reactivity (yellow) rating all use a numbering scale ranging from 0 to 4. A value of zero means that the element poses no hazard; a rating of four indicates extreme danger.
NFPA Fire Rating | 0 | Will not burn |
NFPA Health Rating | 2 | Flash Points Above 37.8°C (100°F) not exceeding 93.3°C (200°F) |
NFPA Reactivity Rating | 0 | Will not burn |
NFPA Hazards |
Autoignition Point | - |
Flashpoint | - |
Database Search
List of unique identifiers to search the element in various chemical registry databases
Database | Identifier number |
---|---|
CAS Number - Chemical Abstracts Service (CAS) | CAS7782-49-2 |
RTECS Number | {N/A, RTECSVS7700000, N/A} |
CID Number | {CID6326970, CID6326970, CID139346} |
Gmelin Number | - |
NSC Number | - |
Compare Selenium with other elements
Compare Selenium with Group 16, Period 4 and Other Nonmetal elements of the periodic table.
Compare Selenium with all Group 16 elements
Compare Selenium with all Period 4 elements
Compare Selenium with all Other Nonmetal elements
Frequently Asked Questions (FAQ)
Find the answers to the most frequently asked questions about Selenium