I - Iodine
Iodine Element Information, Facts, Properties, Trends, Uses, Comparison with other elements
Iodine is a chemical element with symbol I and atomic number 53. The name is from Greek ἰοειδής ioeidēs, meaning violet or purple, due to the color of iodine vapor. Iodine and its compounds are primarily used in nutrition, and industrially in the production of acetic acid and certain polymers.
It belongs to group 17 of the periodic table having trivial name halogens. You can also download Printable Periodic Table of Elements Flashcards for Iodine in a PDF format.
Iodine Facts
Read key information and facts about element Iodine
Name | Iodine |
Atomic Number | 53 |
Atomic Symbol | I |
Atomic Weight | 126.90447 |
Phase | Solid |
Color | SlateGray |
Appearance | lustrous metallic gray, violet as a gas |
Classification | Halogens |
Natural Occurance | Primordial |
Group in Periodic Table | 17 |
Group Name | fluorine family |
Period in Periodic Table | period 5 |
Block in Periodic Table | p-block |
Electronic Configuration | [Kr] 4d10 5s2 5p5 |
Electronic Shell Structure (Electrons per shell) | 2, 8, 18, 18, 7 |
Melting Point | 386.85 K |
Boiling Point | 457.4 K |
CAS Number | CAS7553-56-2 |
How to Locate Iodine on Periodic Table
Periodic table is arranged by atomic number, number of protons in the nucleus which is same as number of electrons. The atomic number increases from left to right. Periodic table starts at top left ( Atomic number 1) and ends at bottom right (atomic number 118). Therefore you can directly look for atomic number 53 to find Iodine on periodic table.
Another way to read periodic table and locate an element is by using group number (column) and period number (row). To locate Iodine on periodic table look for cross section of group 17 and period 5 in the modern periodic table.
Iodine History
The element Iodine was discovered by B. Courtois in year 1811 in France. Iodine was first isolated by B. Courtois in 1811. Iodine derived its name from French iode (after the Greek ioeides, 'violet').
Discovered By | B. Courtois |
Discovery Date | 1811 in France |
First Isolation | 1811 |
Isolated by | B. Courtois |
Courtois discovered it in the ashes of seaweed.
Iodine Uses
Iodine salts are used in photographic film and as an antiseptic for wounds. The radioactive isotope iodine-131 is used to treat thyroid cancer. It is often added in small quantity to table salt in order to avoid iodine deficiency.
Iodine Presence: Abundance in Nature and Around Us
The table below shows the abundance of Iodine in Universe, Sun, Meteorites, Earth's Crust, Oceans and Human Body.
ppb by weight (1ppb =10^-7 %) | ppb by atoms (1ppb =10^-7 %) | |
---|---|---|
Abundance in Universe | 1 | 0.01 |
Abundance in Sun | - | - |
Abundance in Meteorites | 260 | 30 |
Abundance in Earth's Crust | 490 | 80 |
Abundance in Oceans | 60 | 2.9 |
Abundance in Humans | 200 | 10 |
Crystal Structure of Iodine
The solid state structure of Iodine is Base Centered Orthorhombic.
The Crystal structure can be described in terms of its unit Cell. The unit Cells repeats itself in three dimensional space to form the structure.
Unit Cell Parameters
The unit cell is represented in terms of its lattice parameters, which are the lengths of the cell edges Lattice Constants (a, b and c)
a | b | c |
---|---|---|
718.02 pm | 471.02 pm | 981.03 pm |
and the angles between them Lattice Angles (alpha, beta and gamma).
alpha | beta | gamma |
---|---|---|
π/2 | π/2 | π/2 |
The positions of the atoms inside the unit cell are described by the set of atomic positions ( xi, yi, zi) measured from a reference lattice point.
The symmetry properties of the crystal are described by the concept of space groups. All possible symmetric arrangements of particles in three-dimensional space are described by the 230 space groups (219 distinct types, or 230 if chiral copies are considered distinct.
Space Group Name | Cmca |
Space Group Number | 64 |
Crystal Structure | Base Centered Orthorhombic |
Number of atoms per unit cell | 2 |
The number of atoms per unit cell in a simple cubic, face-centered cubic and body-centred cubic are 1,4,2 respectively.
Iodine Atomic and Orbital Properties
Iodine atoms have 53 electrons and the electronic shell structure is [2, 8, 18, 18, 7] with Atomic Term Symbol (Quantum Numbers) 2P3/2.
Atomic Number | 53 |
Number of Electrons (with no charge) | 53 |
Number of Protons | 53 |
Mass Number | 127 |
Number of Neutrons | 74 |
Shell structure (Electrons per energy level) | 2, 8, 18, 18, 7 |
Electron Configuration | [Kr] 4d10 5s2 5p5 |
Valence Electrons | 5s2 5p5 |
Valence (Valency) | 7 |
Main Oxidation States | -1, 1, 3, 5, 7 |
Oxidation States | -1, 1, 2, 3, 4, 5, 6, 7 |
Atomic Term Symbol (Quantum Numbers) | 2P3/2 |
Bohr Atomic Model of Iodine - Electrons per energy level
n | s | p | d | f |
---|
Ground State Electronic Configuration of Iodine - neutral Iodine atom
Abbreviated electronic configuration of Iodine
The ground state abbreviated electronic configuration of Neutral Iodine atom is [Kr] 4d10 5s2 5p5. The portion of Iodine configuration that is equivalent to the noble gas of the preceding period, is abbreviated as [Kr]. For atoms with many electrons, this notation can become lengthy and so an abbreviated notation is used. This is important as it is the Valence electrons 5s2 5p5, electrons in the outermost shell that determine the chemical properties of the element.
Unabbreviated electronic configuration of neutral Iodine
Complete ground state electronic configuration for the Iodine atom, Unabbreviated electronic configuration
1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6 4d10 5s2 5p5
Electrons are filled in atomic orbitals as per the order determined by the Aufbau principle, Pauli Exclusion Principle and Hund’s Rule.
As per the Aufbau principle the electrons will occupy the orbitals having lower energies before occupying higher energy orbitals. According to this principle, electrons are filled in the following order: 1s, 2s, 2p, 3s, 3p, 4s, 3d, 4p, 5s, 4d, 5p, 6s, 4f, 5d, 6p, 7s, 5f, 6d, 7p…
The Pauli exclusion principle states that a maximum of two electrons, each having opposite spins, can fit in an orbital.
Hund's rule states that every orbital in a given subshell is singly occupied by electrons before a second electron is filled in an orbital.
Atomic Structure of Iodine
Iodine atomic radius is 115 pm, while it's covalent radius is 133 pm.
Atomic Radius Calculated | 115 pm(1.15 Å) |
Atomic Radius Empirical | 140 pm (1.4 Å) |
Atomic Volume | 25.689 cm3/mol |
Covalent Radius | 133 pm (1.33 Å) |
Van der Waals Radius | 198 pm |
Neutron Cross Section | 6.2 |
Neutron Mass Absorption | 0.0018 |
Spectral Lines of Iodine - Atomic Spectrum of Iodine
A spectral line is a dark or bright line in an otherwise uniform and continuous spectrum, resulting from an excess or deficiency of photons in a narrow frequency range, compared with the nearby frequencies. Spectral lines are often used to identify atoms and molecules.
Spectral lines are the result of interaction between a quantum system and a single photon. A spectral line may be observed either as an emission line or an absorption line.
Spectral lines are highly atom-specific, and can be used to identify the chemical composition of any medium. Several elements, including helium, thallium, and caesium, were discovered by spectroscopic means. They are widely used to determine the physical conditions of stars and other celestial bodies that cannot be analyzed by other means.
Emission spectrum of Iodine
Absorption spectrum of Iodine
Iodine Chemical Properties: Iodine Ionization Energies and electron affinity
The electron affinity of Iodine is 295.2 kJ/mol.
Valence | 7 |
Electronegativity | 2.66 |
ElectronAffinity | 295.2 kJ/mol |
Ionization Energy of Iodine
Ionization energy is the amount of energy required to remove an electron from an atom or molecule.in chemistry, this energy is expresed in kilocalories per mole (kcal/mol) or kilojoules per mole (kJ/mol).
Refer to table below for Ionization energies of Iodine
Ionization energy number | Enthalpy - kJ/mol |
---|---|
1st | 1008.4 |
2nd | 1845.9 |
3rd | 3180 |
Iodine Physical Properties
Refer to below table for Iodine Physical Properties
Density | 4.94 g/cm3 |
Molar Volume | 25.689 cm3/mol |
Elastic Properties
Young Modulus | - |
Shear Modulus | - |
Bulk Modulus | 7.7 GPa |
Poisson Ratio | - |
Hardness of Iodine - Tests to Measure of Hardness of Element
Mohs Hardness | - |
Vickers Hardness | - |
Brinell Hardness | - |
Iodine Electrical Properties
Electrical resistivity measures element's electrical resistance or how strongly it resists electric current.The SI unit of electrical resistivity is the ohm-metre (Ω⋅m). While Electrical conductivity is the reciprocal of electrical resistivity. It represents a element's ability to conduct electric current. The SI unit of electrical conductivity is siemens per metre (S/m).
Iodine is a Insulator. Refer to table below for the Electrical properties of Iodine
Electrical conductors | Insulator |
Electrical Conductivity | 1e-7 S/m |
Resistivity | 10000000 m Ω |
Superconducting Point | - |
Iodine Heat and Conduction Properties
Thermal Conductivity | 0.449 W/(m K) |
Thermal Expansion | - |
Iodine Magnetic Properties
Magnetic Type | Diamagnetic |
Curie Point | - |
Mass Magnetic Susceptibility | -4.5e-9 m3/kg |
Molar Magnetic Susceptibility | -1.14e-9 m3/mol |
Volume Magnetic Susceptibility | -0.0000222 |
Optical Properties of Iodine
Refractive Index | - |
Acoustic Properties of Iodine
Speed of Sound | - |
Iodine Thermal Properties - Enthalpies and thermodynamics
Refer to table below for Thermal properties of Iodine
Melting Point | 386.85 K(113.70 °C, 236.660 °F) |
Boiling Point | 457.4 K(184.25 °C, 363.650 °F) |
Critical Temperature | 819 K |
Superconducting Point | - |
Enthalpies of Iodine
Heat of Fusion | 7.76 kJ/mol |
Heat of Vaporization | 20.9 kJ/mol |
Heat of Combustion | - |
Iodine Isotopes - Nuclear Properties of Iodine
Iodine has 37 isotopes, with between 108 and 144 nucleons. Iodine has 1 stable naturally occuring isotopes.
Isotopes of Iodine - Naturally occurring stable Isotopes: 127I.
Isotope | Z | N | Isotope Mass | % Abundance | T half | Decay Mode |
---|---|---|---|---|---|---|
108I | 53 | 55 | 108 | Synthetic | ||
109I | 53 | 56 | 109 | Synthetic | ||
110I | 53 | 57 | 110 | Synthetic | ||
111I | 53 | 58 | 111 | Synthetic | ||
112I | 53 | 59 | 112 | Synthetic | ||
113I | 53 | 60 | 113 | Synthetic | ||
114I | 53 | 61 | 114 | Synthetic | ||
115I | 53 | 62 | 115 | Synthetic | ||
116I | 53 | 63 | 116 | Synthetic | ||
117I | 53 | 64 | 117 | Synthetic | ||
118I | 53 | 65 | 118 | Synthetic | ||
119I | 53 | 66 | 119 | Synthetic | ||
120I | 53 | 67 | 120 | Synthetic | ||
121I | 53 | 68 | 121 | Synthetic | ||
122I | 53 | 69 | 122 | Synthetic | ||
123I | 53 | 70 | 123 | Synthetic | ||
124I | 53 | 71 | 124 | Synthetic | ||
125I | 53 | 72 | 125 | Synthetic | ||
126I | 53 | 73 | 126 | Synthetic | ||
127I | 53 | 74 | 127 | 100% | Stable | |
128I | 53 | 75 | 128 | Synthetic | ||
129I | 53 | 76 | 129 | Synthetic | ||
130I | 53 | 77 | 130 | Synthetic | ||
131I | 53 | 78 | 131 | Synthetic | ||
132I | 53 | 79 | 132 | Synthetic | ||
133I | 53 | 80 | 133 | Synthetic | ||
134I | 53 | 81 | 134 | Synthetic | ||
135I | 53 | 82 | 135 | Synthetic | ||
136I | 53 | 83 | 136 | Synthetic | ||
137I | 53 | 84 | 137 | Synthetic | ||
138I | 53 | 85 | 138 | Synthetic | ||
139I | 53 | 86 | 139 | Synthetic | ||
140I | 53 | 87 | 140 | Synthetic | ||
141I | 53 | 88 | 141 | Synthetic | ||
142I | 53 | 89 | 142 | Synthetic | ||
143I | 53 | 90 | 143 | Synthetic | ||
144I | 53 | 91 | 144 | Synthetic |
Regulatory and Health - Health and Safety Parameters and Guidelines
The United States Department of Transportation (DOT) identifies hazard class of all dangerous elements/goods/commodities either by its class (or division) number or name. The DOT has divided these materials into nine different categories, known as Hazard Classes.
NFPA 704 is a Standard System for the Identification of the Hazards of Materials for Emergency Response. NFPA is a standard maintained by the US based National Fire Protection Association.
The health (blue), flammability (red), and reactivity (yellow) rating all use a numbering scale ranging from 0 to 4. A value of zero means that the element poses no hazard; a rating of four indicates extreme danger.
NFPA Fire Rating | 0 | Will not burn |
NFPA Health Rating | 3 | Flash Points below 37.8°C (100°F) |
NFPA Reactivity Rating | 0 | Will not burn |
NFPA Hazards |
Autoignition Point | - |
Flashpoint | - |
Database Search
List of unique identifiers to search the element in various chemical registry databases
Database | Identifier number |
---|---|
CAS Number - Chemical Abstracts Service (CAS) | CAS7553-56-2 |
RTECS Number | RTECSNN1575000 |
CID Number | CID807 |
Gmelin Number | - |
NSC Number | - |
Compare Iodine with other elements
Compare Iodine with Group 17, Period 5 and Halogens elements of the periodic table.
Compare Iodine with all Group 17 elements
Compare Iodine with all Period 5 elements
Compare Iodine with all Halogens elements
Frequently Asked Questions (FAQ)
Find the answers to the most frequently asked questions about Iodine