Germanium Element Information, Facts, Properties, Trends, Uses, Comparison with other elements
Germanium is a chemical element with symbol Ge and atomic number 32. It is a lustrous, hard, grayish-white Metalloid in the carbon group, chemically similar to its group neighbors tin and silicon. Purified germanium is a semiconductor, with an appearance most similar to elemental silicon.
It belongs to group 14 of the periodic table having trivial name tetrels, crystallogens. You can also download Printable Periodic Table of Elements Flashcards for Germanium in a PDF format.
Germanium Facts
Read key information and facts about element Germanium
Name | Germanium |
Atomic Number | 32 |
Atomic Symbol | Ge |
Atomic Weight | 72.64 |
Phase | Solid |
Color | Gray |
Appearance | grayish-white |
Classification | Metalloid |
Natural Occurance | Primordial |
Group in Periodic Table | 14 |
Group Name | carbon family |
Period in Periodic Table | period 4 |
Block in Periodic Table | p-block |
Electronic Configuration | [Ar] 3d10 4s2 4p2 |
Electronic Shell Structure (Electrons per shell) | 2, 8, 18, 4 |
Melting Point | 1211.4 K |
Boiling Point | 3093 K |
CAS Number | CAS7440-56-4 |
How to Locate Germanium on Periodic Table
Periodic table is arranged by atomic number, number of protons in the nucleus which is same as number of electrons. The atomic number increases from left to right. Periodic table starts at top left ( Atomic number 1) and ends at bottom right (atomic number 118). Therefore you can directly look for atomic number 32 to find Germanium on periodic table.
Another way to read periodic table and locate an element is by using group number (column) and period number (row). To locate Germanium on periodic table look for cross section of group 14 and period 4 in the modern periodic table.
Germanium History
The element Germanium was discovered by C. A. Winkler in year 1886 in Germany. Germanium was first isolated by in . Germanium derived its name from Germania, the Latin name for Germany.
Discovered By | C. A. Winkler |
Discovery Date | 1886 in Germany |
First Isolation | |
Isolated by |
In February 1886 Winkler found inargyroditethe eka-silicon that Mendeleev had predicted in 1871.
Germanium Uses
Germanium is majorly used in the semiconductor industry. When it is loaded with other elements, it makes highly efficient transistors. It is also implemented in fluorescent lamps.
Germanium Presence: Abundance in Nature and Around Us
The table below shows the abundance of Germanium in Universe, Sun, Meteorites, Earth's Crust, Oceans and Human Body.
ppb by weight (1ppb =10^-7 %) | ppb by atoms (1ppb =10^-7 %) | |
---|---|---|
Abundance in Universe | 200 | 3 |
Abundance in Sun | 200 | 3 |
Abundance in Meteorites | 21000 | 4900 |
Abundance in Earth's Crust | 1400 | 390 |
Abundance in Oceans | 0.06 | 0.0051 |
Abundance in Humans | - | - |
Crystal Structure of Germanium
The solid state structure of Germanium is Face Centered Cubic.
The Crystal structure can be described in terms of its unit Cell. The unit Cells repeats itself in three dimensional space to form the structure.
Unit Cell Parameters
The unit cell is represented in terms of its lattice parameters, which are the lengths of the cell edges Lattice Constants (a, b and c)
a | b | c |
---|---|---|
565.75 pm | 565.75 pm | 565.75 pm |
and the angles between them Lattice Angles (alpha, beta and gamma).
alpha | beta | gamma |
---|---|---|
π/2 | π/2 | π/2 |
The positions of the atoms inside the unit cell are described by the set of atomic positions ( xi, yi, zi) measured from a reference lattice point.
The symmetry properties of the crystal are described by the concept of space groups. All possible symmetric arrangements of particles in three-dimensional space are described by the 230 space groups (219 distinct types, or 230 if chiral copies are considered distinct.
Space Group Name | Fm_ 3m |
Space Group Number | 225 |
Crystal Structure | Face Centered Cubic |
Number of atoms per unit cell | 4 |
The number of atoms per unit cell in a simple cubic, face-centered cubic and body-centred cubic are 1,4,2 respectively.
Germanium Atomic and Orbital Properties
Germanium atoms have 32 electrons and the electronic shell structure is [2, 8, 18, 4] with Atomic Term Symbol (Quantum Numbers) 3P0.
Atomic Number | 32 |
Number of Electrons (with no charge) | 32 |
Number of Protons | 32 |
Mass Number | 73 |
Number of Neutrons | 41 |
Shell structure (Electrons per energy level) | 2, 8, 18, 4 |
Electron Configuration | [Ar] 3d10 4s2 4p2 |
Valence Electrons | 4s2 4p2 |
Valence (Valency) | 4 |
Main Oxidation States | -4, 2, 4 |
Oxidation States | -4, -3, -2, -1, 0, 1, 2, 3, 4 |
Atomic Term Symbol (Quantum Numbers) | 3P0 |
Bohr Atomic Model of Germanium - Electrons per energy level
n | s | p | d | f |
---|
Ground State Electronic Configuration of Germanium - neutral Germanium atom
Abbreviated electronic configuration of Germanium
The ground state abbreviated electronic configuration of Neutral Germanium atom is [Ar] 3d10 4s2 4p2. The portion of Germanium configuration that is equivalent to the noble gas of the preceding period, is abbreviated as [Ar]. For atoms with many electrons, this notation can become lengthy and so an abbreviated notation is used. This is important as it is the Valence electrons 4s2 4p2, electrons in the outermost shell that determine the chemical properties of the element.
Unabbreviated electronic configuration of neutral Germanium
Complete ground state electronic configuration for the Germanium atom, Unabbreviated electronic configuration
1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p2
Electrons are filled in atomic orbitals as per the order determined by the Aufbau principle, Pauli Exclusion Principle and Hund’s Rule.
As per the Aufbau principle the electrons will occupy the orbitals having lower energies before occupying higher energy orbitals. According to this principle, electrons are filled in the following order: 1s, 2s, 2p, 3s, 3p, 4s, 3d, 4p, 5s, 4d, 5p, 6s, 4f, 5d, 6p, 7s, 5f, 6d, 7p…
The Pauli exclusion principle states that a maximum of two electrons, each having opposite spins, can fit in an orbital.
Hund's rule states that every orbital in a given subshell is singly occupied by electrons before a second electron is filled in an orbital.
Atomic Structure of Germanium
Germanium atomic radius is 125 pm, while it's covalent radius is 122 pm.
Atomic Radius Calculated | 125 pm(1.25 Å) |
Atomic Radius Empirical | 125 pm (1.25 Å) |
Atomic Volume | 13.646 cm3/mol |
Covalent Radius | 122 pm (1.22 Å) |
Van der Waals Radius | 211 pm |
Neutron Cross Section | 2.2 |
Neutron Mass Absorption | 0.0011 |
Spectral Lines of Germanium - Atomic Spectrum of Germanium
A spectral line is a dark or bright line in an otherwise uniform and continuous spectrum, resulting from an excess or deficiency of photons in a narrow frequency range, compared with the nearby frequencies. Spectral lines are often used to identify atoms and molecules.
Spectral lines are the result of interaction between a quantum system and a single photon. A spectral line may be observed either as an emission line or an absorption line.
Spectral lines are highly atom-specific, and can be used to identify the chemical composition of any medium. Several elements, including helium, thallium, and caesium, were discovered by spectroscopic means. They are widely used to determine the physical conditions of stars and other celestial bodies that cannot be analyzed by other means.
Emission spectrum of Germanium
Absorption spectrum of Germanium
Germanium Chemical Properties: Germanium Ionization Energies and electron affinity
The electron affinity of Germanium is 119 kJ/mol.
Valence | 4 |
Electronegativity | 2.01 |
ElectronAffinity | 119 kJ/mol |
Ionization Energy of Germanium
Ionization energy is the amount of energy required to remove an electron from an atom or molecule.in chemistry, this energy is expresed in kilocalories per mole (kcal/mol) or kilojoules per mole (kJ/mol).
Refer to table below for Ionization energies of Germanium
Ionization energy number | Enthalpy - kJ/mol |
---|---|
1st | 762 |
2nd | 1537.5 |
3rd | 3302.1 |
4th | 4411 |
5th | 9020 |
Germanium Physical Properties
Refer to below table for Germanium Physical Properties
Density | 5.323 g/cm3(when liquid at m.p density is $5.6 g/cm3) |
Molar Volume | 13.646 cm3/mol |
Elastic Properties
Young Modulus | - |
Shear Modulus | - |
Bulk Modulus | - |
Poisson Ratio | - |
Hardness of Germanium - Tests to Measure of Hardness of Element
Mohs Hardness | 6 MPa |
Vickers Hardness | - |
Brinell Hardness | - |
Germanium Electrical Properties
Electrical resistivity measures element's electrical resistance or how strongly it resists electric current.The SI unit of electrical resistivity is the ohm-metre (Ω⋅m). While Electrical conductivity is the reciprocal of electrical resistivity. It represents a element's ability to conduct electric current. The SI unit of electrical conductivity is siemens per metre (S/m).
Germanium is a Semiconductor. Refer to table below for the Electrical properties of Germanium
Electrical conductors | Semiconductor |
Electrical Conductivity | 2000 S/m |
Resistivity | 0.0005 m Ω |
Superconducting Point | - |
Germanium Heat and Conduction Properties
Thermal Conductivity | 60 W/(m K) |
Thermal Expansion | 0.000006 /K |
Germanium Magnetic Properties
Magnetic Type | Diamagnetic |
Curie Point | - |
Mass Magnetic Susceptibility | -1.5e-9 m3/kg |
Molar Magnetic Susceptibility | -1.09e-10 m3/mol |
Volume Magnetic Susceptibility | -0.00000798 |
Optical Properties of Germanium
Refractive Index | - |
Acoustic Properties of Germanium
Speed of Sound | 5400 m/s |
Germanium Thermal Properties - Enthalpies and thermodynamics
Refer to table below for Thermal properties of Germanium
Melting Point | 1211.4 K(938.25 °C, 1720.850 °F) |
Boiling Point | 3093 K(2819.85 °C, 5107.730 °F) |
Critical Temperature | - |
Superconducting Point | - |
Enthalpies of Germanium
Heat of Fusion | 31.8 kJ/mol |
Heat of Vaporization | 334 kJ/mol |
Heat of Combustion | -536 J/(kg K) |
Germanium Isotopes - Nuclear Properties of Germanium
Germanium has 32 isotopes, with between 58 and 89 nucleons. Germanium has 4 stable naturally occuring isotopes.
Isotopes of Germanium - Naturally occurring stable Isotopes: 70Ge, 72Ge, 73Ge, 74Ge.
Isotope | Z | N | Isotope Mass | % Abundance | T half | Decay Mode |
---|---|---|---|---|---|---|
58Ge | 32 | 26 | 58 | Synthetic | ||
59Ge | 32 | 27 | 59 | Synthetic | ||
60Ge | 32 | 28 | 60 | Synthetic | ||
61Ge | 32 | 29 | 61 | Synthetic | ||
62Ge | 32 | 30 | 62 | Synthetic | ||
63Ge | 32 | 31 | 63 | Synthetic | ||
64Ge | 32 | 32 | 64 | Synthetic | ||
65Ge | 32 | 33 | 65 | Synthetic | ||
66Ge | 32 | 34 | 66 | Synthetic | ||
67Ge | 32 | 35 | 67 | Synthetic | ||
68Ge | 32 | 36 | 68 | Synthetic | ||
69Ge | 32 | 37 | 69 | Synthetic | ||
70Ge | 32 | 38 | 70 | 20.84% | Stable | N/A |
71Ge | 32 | 39 | 71 | Synthetic | ||
72Ge | 32 | 40 | 72 | 27.54% | Stable | N/A |
73Ge | 32 | 41 | 73 | 7.73% | Stable | |
74Ge | 32 | 42 | 74 | 36.28% | Stable | N/A |
75Ge | 32 | 43 | 75 | Synthetic | ||
76Ge | 32 | 44 | 76 | 7.61% | Stable | N/A |
77Ge | 32 | 45 | 77 | Synthetic | ||
78Ge | 32 | 46 | 78 | Synthetic | ||
79Ge | 32 | 47 | 79 | Synthetic | ||
80Ge | 32 | 48 | 80 | Synthetic | ||
81Ge | 32 | 49 | 81 | Synthetic | ||
82Ge | 32 | 50 | 82 | Synthetic | ||
83Ge | 32 | 51 | 83 | Synthetic | ||
84Ge | 32 | 52 | 84 | Synthetic | ||
85Ge | 32 | 53 | 85 | Synthetic | ||
86Ge | 32 | 54 | 86 | Synthetic | ||
87Ge | 32 | 55 | 87 | Synthetic | ||
88Ge | 32 | 56 | 88 | Synthetic | ||
89Ge | 32 | 57 | 89 | Synthetic |
Regulatory and Health - Health and Safety Parameters and Guidelines
The United States Department of Transportation (DOT) identifies hazard class of all dangerous elements/goods/commodities either by its class (or division) number or name. The DOT has divided these materials into nine different categories, known as Hazard Classes.
DOT Numbers | 3089 |
DOT Hazard Class | 4.1 |
NFPA 704 is a Standard System for the Identification of the Hazards of Materials for Emergency Response. NFPA is a standard maintained by the US based National Fire Protection Association.
The health (blue), flammability (red), and reactivity (yellow) rating all use a numbering scale ranging from 0 to 4. A value of zero means that the element poses no hazard; a rating of four indicates extreme danger.
NFPA Fire Rating | 0 | Will not burn |
NFPA Health Rating | 1 | Flash Points Above 93.3°C (200°F) |
NFPA Reactivity Rating | 0 | Will not burn |
NFPA Hazards |
Autoignition Point | - |
Flashpoint | - |
Database Search
List of unique identifiers to search the element in various chemical registry databases
Database | Identifier number |
---|---|
CAS Number - Chemical Abstracts Service (CAS) | CAS7440-56-4 |
RTECS Number | RTECSLY5200000 |
CID Number | CID6326954 |
Gmelin Number | - |
NSC Number | - |
Compare Germanium with other elements
Compare Germanium with Group 14, Period 4 and Metalloid elements of the periodic table.
Compare Germanium with all Group 14 elements
Compare Germanium with all Period 4 elements
Compare Germanium with all Metalloid elements
Frequently Asked Questions (FAQ)
Find the answers to the most frequently asked questions about Germanium