F - Fluorine
Fluorine Element Information, Facts, Properties, Trends, Uses, Comparison with other elements
Fluorine is a chemical element with symbol F and atomic number 9. It is the lightest halogen and exists as a highly toxic pale yellow diatomic gas at standard conditions. As the most electronegative element, it is extremely reactive:almost all other elements, including some noble gases, form compounds with fluorine.
It belongs to group 17 of the periodic table having trivial name halogens. You can also download Printable Periodic Table of Elements Flashcards for Fluorine in a PDF format.
Fluorine Facts
Read key information and facts about element Fluorine
Name | Fluorine |
Atomic Number | 9 |
Atomic Symbol | F |
Atomic Weight | 18.9984032 |
Phase | Gas(Diatomic Gas) |
Color | Colorless |
Appearance | - |
Classification | Halogens |
Natural Occurance | Primordial |
Group in Periodic Table | 17 |
Group Name | fluorine family |
Period in Periodic Table | period 2 |
Block in Periodic Table | p-block |
Electronic Configuration | [He] 2s2 2p5 |
Electronic Shell Structure (Electrons per shell) | 2, 7 |
Melting Point | 53.5 K |
Boiling Point | 85.03 K |
CAS Number | CAS7782-41-4 |
How to Locate Fluorine on Periodic Table
Periodic table is arranged by atomic number, number of protons in the nucleus which is same as number of electrons. The atomic number increases from left to right. Periodic table starts at top left ( Atomic number 1) and ends at bottom right (atomic number 118). Therefore you can directly look for atomic number 9 to find Fluorine on periodic table.
Another way to read periodic table and locate an element is by using group number (column) and period number (row). To locate Fluorine on periodic table look for cross section of group 17 and period 2 in the modern periodic table.
Fluorine History
The element Fluorine was discovered by A.-M. Ampère in year 1810 in France. Fluorine was first isolated by H. Moissan in 1886. Fluorine derived its name from the Latin fluere, meaning 'to flow'.
Discovered By | A.-M. Ampère |
Discovery Date | 1810 in France |
First Isolation | 1886 |
Isolated by | H. Moissan |
Radical fluorique appears on the list of elements in Lavoisier'sTraité Élémentaire de Chimie from 1789, but radical muriatique also appears instead of chlorine. André-Marie Ampère predicted an element analogous to chlorine obtainable fromhydrofluoric acid, and between 1812 and 1886 many researchers tried to obtain this element. It was eventually isolated by Moissan.
Fluorine Uses
Fluorine is a common addition to drinking water and is used as a cleaning agent in toothpaste. The chemical can dissolve glass and is used mainly as an etching compound. It is also used to make uranium hexafluoride, used by the nuclear power industry to separate uranium isotopes and to make sulfur hexafluoride, the insulating gas for high-power electricity transformers. Fluorine is additionally used in many solvents and high-temperature plastics, such as Teflon and Gore-Tex®.
Fluorine Presence: Abundance in Nature and Around Us
The table below shows the abundance of Fluorine in Universe, Sun, Meteorites, Earth's Crust, Oceans and Human Body.
ppb by weight (1ppb =10^-7 %) | ppb by atoms (1ppb =10^-7 %) | |
---|---|---|
Abundance in Universe | 400 | 30 |
Abundance in Sun | 500 | 30 |
Abundance in Meteorites | 89000 | 96000 |
Abundance in Earth's Crust | 540000 | 590000 |
Abundance in Oceans | 1300 | 420 |
Abundance in Humans | 37000 | 12000 |
Crystal Structure of Fluorine
The solid state structure of Fluorine is Base Centered Monoclinic.
The Crystal structure can be described in terms of its unit Cell. The unit Cells repeats itself in three dimensional space to form the structure.
Unit Cell Parameters
The unit cell is represented in terms of its lattice parameters, which are the lengths of the cell edges Lattice Constants (a, b and c)
a | b | c |
---|---|---|
550 pm | 328 pm | 728 pm |
and the angles between them Lattice Angles (alpha, beta and gamma).
alpha | beta | gamma |
---|---|---|
π/2 | π/2 | π/2 |
The positions of the atoms inside the unit cell are described by the set of atomic positions ( xi, yi, zi) measured from a reference lattice point.
The symmetry properties of the crystal are described by the concept of space groups. All possible symmetric arrangements of particles in three-dimensional space are described by the 230 space groups (219 distinct types, or 230 if chiral copies are considered distinct.
Space Group Name | C12/c1 |
Space Group Number | 15 |
Crystal Structure | Base Centered Monoclinic |
Number of atoms per unit cell |
The number of atoms per unit cell in a simple cubic, face-centered cubic and body-centred cubic are 1,4,2 respectively.
Fluorine Atomic and Orbital Properties
Fluorine atoms have 9 electrons and the electronic shell structure is [2, 7] with Atomic Term Symbol (Quantum Numbers) 2P3/2.
Atomic Number | 9 |
Number of Electrons (with no charge) | 9 |
Number of Protons | 9 |
Mass Number | 19 |
Number of Neutrons | 10 |
Shell structure (Electrons per energy level) | 2, 7 |
Electron Configuration | [He] 2s2 2p5 |
Valence Electrons | 2s2 2p5 |
Valence (Valency) | 1 |
Main Oxidation States | -1 |
Oxidation States | -1, 0 |
Atomic Term Symbol (Quantum Numbers) | 2P3/2 |
Bohr Atomic Model of Fluorine - Electrons per energy level
n | s | p | d | f |
---|
Ground State Electronic Configuration of Fluorine - neutral Fluorine atom
Abbreviated electronic configuration of Fluorine
The ground state abbreviated electronic configuration of Neutral Fluorine atom is [He] 2s2 2p5. The portion of Fluorine configuration that is equivalent to the noble gas of the preceding period, is abbreviated as [He]. For atoms with many electrons, this notation can become lengthy and so an abbreviated notation is used. This is important as it is the Valence electrons 2s2 2p5, electrons in the outermost shell that determine the chemical properties of the element.
Unabbreviated electronic configuration of neutral Fluorine
Complete ground state electronic configuration for the Fluorine atom, Unabbreviated electronic configuration
1s2 2s2 2p5
Electrons are filled in atomic orbitals as per the order determined by the Aufbau principle, Pauli Exclusion Principle and Hund’s Rule.
As per the Aufbau principle the electrons will occupy the orbitals having lower energies before occupying higher energy orbitals. According to this principle, electrons are filled in the following order: 1s, 2s, 2p, 3s, 3p, 4s, 3d, 4p, 5s, 4d, 5p, 6s, 4f, 5d, 6p, 7s, 5f, 6d, 7p…
The Pauli exclusion principle states that a maximum of two electrons, each having opposite spins, can fit in an orbital.
Hund's rule states that every orbital in a given subshell is singly occupied by electrons before a second electron is filled in an orbital.
Atomic Structure of Fluorine
Fluorine atomic radius is 42 pm, while it's covalent radius is 71 pm.
Atomic Radius Calculated | 42 pm(0.42 Å) |
Atomic Radius Empirical | 50 pm (0.5 Å) |
Atomic Volume | 11.202 cm3/mol |
Covalent Radius | 71 pm (0.71 Å) |
Van der Waals Radius | 147 pm |
Neutron Cross Section | 0.0096 |
Neutron Mass Absorption | 0.00002 |
Spectral Lines of Fluorine - Atomic Spectrum of Fluorine
A spectral line is a dark or bright line in an otherwise uniform and continuous spectrum, resulting from an excess or deficiency of photons in a narrow frequency range, compared with the nearby frequencies. Spectral lines are often used to identify atoms and molecules.
Spectral lines are the result of interaction between a quantum system and a single photon. A spectral line may be observed either as an emission line or an absorption line.
Spectral lines are highly atom-specific, and can be used to identify the chemical composition of any medium. Several elements, including helium, thallium, and caesium, were discovered by spectroscopic means. They are widely used to determine the physical conditions of stars and other celestial bodies that cannot be analyzed by other means.
Emission spectrum of Fluorine
Absorption spectrum of Fluorine
Fluorine Chemical Properties: Fluorine Ionization Energies and electron affinity
The electron affinity of Fluorine is 328 kJ/mol.
Valence | 1 |
Electronegativity | 3.98 |
ElectronAffinity | 328 kJ/mol |
Ionization Energy of Fluorine
Ionization energy is the amount of energy required to remove an electron from an atom or molecule.in chemistry, this energy is expresed in kilocalories per mole (kcal/mol) or kilojoules per mole (kJ/mol).
Refer to table below for Ionization energies of Fluorine
Ionization energy number | Enthalpy - kJ/mol |
---|---|
1st | 1681 |
2nd | 3374.2 |
3rd | 6050.4 |
4th | 8407.7 |
5th | 11022.7 |
6th | 15164.1 |
7th | 17868 |
8th | 92038.1 |
9th | 106434.3 |
Fluorine Physical Properties
Refer to below table for Fluorine Physical Properties
Density | 0.001696 g/cm3 |
Molar Volume | 11.202 cm3/mol |
Elastic Properties
Young Modulus | - |
Shear Modulus | - |
Bulk Modulus | - |
Poisson Ratio | - |
Hardness of Fluorine - Tests to Measure of Hardness of Element
Mohs Hardness | - |
Vickers Hardness | - |
Brinell Hardness | - |
Fluorine Electrical Properties
Electrical resistivity measures element's electrical resistance or how strongly it resists electric current.The SI unit of electrical resistivity is the ohm-metre (Ω⋅m). While Electrical conductivity is the reciprocal of electrical resistivity. It represents a element's ability to conduct electric current. The SI unit of electrical conductivity is siemens per metre (S/m).
Fluorine is a -. Refer to table below for the Electrical properties of Fluorine
Electrical conductors | - |
Electrical Conductivity | - |
Resistivity | - |
Superconducting Point | - |
Fluorine Heat and Conduction Properties
Thermal Conductivity | 0.0277 W/(m K) |
Thermal Expansion | - |
Fluorine Magnetic Properties
Magnetic Type | - |
Curie Point | - |
Mass Magnetic Susceptibility | - |
Molar Magnetic Susceptibility | - |
Volume Magnetic Susceptibility | - |
Optical Properties of Fluorine
Refractive Index | 1.000195 |
Acoustic Properties of Fluorine
Speed of Sound | - |
Fluorine Thermal Properties - Enthalpies and thermodynamics
Refer to table below for Thermal properties of Fluorine
Melting Point | 53.5 K(-219.65 °C, -363.370 °F) |
Boiling Point | 85.03 K(-188.12 °C, -306.616 °F) |
Critical Temperature | 144.13 K |
Superconducting Point | - |
Enthalpies of Fluorine
Heat of Fusion | 0.26 kJ/mol |
Heat of Vaporization | 3.27 kJ/mol |
Heat of Combustion | - |
Fluorine Isotopes - Nuclear Properties of Fluorine
Fluorine has 18 isotopes, with between 14 and 31 nucleons. Fluorine has 1 stable naturally occuring isotopes.
Isotopes of Fluorine - Naturally occurring stable Isotopes: 19F.
Isotope | Z | N | Isotope Mass | % Abundance | T half | Decay Mode |
---|---|---|---|---|---|---|
14F | 9 | 5 | 14 | Synthetic | ||
15F | 9 | 6 | 15 | Synthetic | ||
16F | 9 | 7 | 16 | Synthetic | ||
17F | 9 | 8 | 17 | Synthetic | ||
18F | 9 | 9 | 18 | Synthetic | ||
19F | 9 | 10 | 19 | 100% | Stable | |
20F | 9 | 11 | 20 | Synthetic | ||
21F | 9 | 12 | 21 | Synthetic | ||
22F | 9 | 13 | 22 | Synthetic | ||
23F | 9 | 14 | 23 | Synthetic | ||
24F | 9 | 15 | 24 | Synthetic | ||
25F | 9 | 16 | 25 | Synthetic | ||
26F | 9 | 17 | 26 | Synthetic | ||
27F | 9 | 18 | 27 | Synthetic | ||
28F | 9 | 19 | 28 | Synthetic | ||
29F | 9 | 20 | 29 | Synthetic | ||
30F | 9 | 21 | 30 | Synthetic | ||
31F | 9 | 22 | 31 | Synthetic |
Regulatory and Health - Health and Safety Parameters and Guidelines
The United States Department of Transportation (DOT) identifies hazard class of all dangerous elements/goods/commodities either by its class (or division) number or name. The DOT has divided these materials into nine different categories, known as Hazard Classes.
DOT Numbers | 9192 |
DOT Hazard Class | 2.3 |
NFPA 704 is a Standard System for the Identification of the Hazards of Materials for Emergency Response. NFPA is a standard maintained by the US based National Fire Protection Association.
The health (blue), flammability (red), and reactivity (yellow) rating all use a numbering scale ranging from 0 to 4. A value of zero means that the element poses no hazard; a rating of four indicates extreme danger.
NFPA Fire Rating | 0 | Will not burn |
NFPA Health Rating | 4 | Flash Points below 22.8°C (73°F) |
NFPA Reactivity Rating | 4 | Flash Points below 22.8°C (73°F) |
NFPA Hazards | OX | Oxidizing Agent, Water Reactive |
Autoignition Point | - |
Flashpoint | - |
Database Search
List of unique identifiers to search the element in various chemical registry databases
Database | Identifier number |
---|---|
CAS Number - Chemical Abstracts Service (CAS) | CAS7782-41-4 |
RTECS Number | RTECSLM6475000 |
CID Number | CID24524 |
Gmelin Number | Gmelin16281 |
NSC Number | - |
Compare Fluorine with other elements
Compare Fluorine with Group 17, Period 2 and Halogens elements of the periodic table.
Compare Fluorine with all Group 17 elements
Compare Fluorine with all Period 2 elements
Compare Fluorine with all Halogens elements
Frequently Asked Questions (FAQ)
Find the answers to the most frequently asked questions about Fluorine